The driver of the Chevrolet was pronounced dead at the scene.
The driver of the Toyota was taken to Miami Valley Hospital with injuries that were not life-threatening.
The crash remains under investigation.
One person was killed Sunday in a crash on Germantown Pike in Jefferson Twp.
Crews were called around 8:30 p.m. to the 5000 block of Germantown Pike, the Montgomery County Sheriff’s Office said. A Chevrolet traveling south went left of center and struck a Toyota headed north.