Greene allowed two runs and two hits in one inning.
Greene made the All-Star team for the first time along with teammate Elly De La Cruz, who went 1-for-2 with a single in the seventh inning and a groundout in the ninth.
Greene is the first Red to be the winning or losing pitcher in the All-Star Game since Mario Soto, who took the loss in 1983. Ewell Blackwell was the last Red to earn a victory in the All-Star Game in 1950.
The American League has won 10 of the last 11 All-Star Games and is 28-7-1 against the National League since 1988.
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